O2 Sensor Contamination
WARNING: This page does not describe the selected car, but rather 9 other vehicles, including the 1990 Pontiac Grand Am, 1990 Pontiac 6000, 1990 Oldsmobile Cutlass Cruiser, 1990 Oldsmobile Cutlass Ciera, and 1990 Oldsmobile Cutlass Calais. However, it is still accessible from the selected car via links, so may be relevant.
O2 sensor contamination, caused by silicone in certain fuels or use of improper RTV sealant, may cause a White powdery coating to cover the exterior of the O2 sensor. The false high signal voltage (low oxygen content sensed) produced is interpreted by the ECM as a rich mixture, causing the ECM to set Code 45.